Keycard and Keycard Shell work together with a wallet app that supports QR signing to initiate and sign transactions. You must connect your Keycard Shell to a wallet app to initiate the transaction, then use your Keycard Shell to sign the transaction.
In this process, your wallet app shows a QR code with the transaction, which you scan with Keycard Shell. Then, you scan the Keycard Shell's QR code with your wallet to complete the transaction.
If you have multiple accounts in your wallet app, be sure to select the one you want to use for the transaction, and confirm it comes from your Keycard.